Correlation of Reaction Rate Constants in Mixed Liquid Solvents

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  • KATO Haruo
    Department of Chemical Engineering, Ichinoseki National College of Technology
  • YONEZAWA Setsuko
    Department of Chemical Engineering, Faculty of Engineering
  • ARAI Yasuhiko
    Department of Chemical Engineering, Faculty of Engineering

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Other Title
  • 液体混合溶媒中の反応速度定数の相関
  • エキタイ コンゴウ ヨウバイ チュウ ノ ハンノウ ソクド テイスウ ノ ソウカン

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An empirical method has been proposed to correlate the reaction rate constants in mixed liquid solvents based on the Arrhenius equation. A Redlich-Kister type excess function is introduced to obtain the excess activation energy in the mixed solvent. The rate constants for isoprenemaleic anhydride reaction in dilute solution of the hexane + nitrobenzene mixture previously reported was examined. It is found that the present model can correlated the reaction rate constants with a good agreement.

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