琵琶湖・淀川水系河川水中におけるトリハロメタン前駆物質としての溶存有機物質の分画

  • 永井 健一
    京都工芸繊維大学大学院工芸科学研究科物質工学専攻
  • 青木 眞一
    京都工芸繊維大学大学院工芸科学研究科物質工学専攻
  • 布施 泰朗
    京都工芸繊維大学環境科学センター
  • 山田 悦
    京都工芸繊維大学大学院工芸科学研究科物質工学専攻 京都工芸繊維大学環境科学センター

書誌事項

タイトル別名
  • Fractionation of Dissolved Organic Matter (DOM) as Precursors of Trihalomethane in Lake Biwa and Yodo Rivers
  • ビワコ ヨドガワ スイケイ カセン スイチュウ ニ オケル トリハロメタン ゼンク ブッシツ ト シテ ノ ヨウゾン ユウキ ブッシツ ノ ブンカク

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抄録

In order to clarify the precursors of trihalomethane (THM) in tap water, humic substances and other dissolved organic matter (DOM) in Lake Biwa and Yodo rivers were investigated to elucidate their behavior and contribution to the THM formation potential. The hydrophobic and hydrophilic fractions of DOM were isolated using XAD-7HP resin, and then the THM formation potential with the chlorination of these fractions was examined. Hydrophobic acids, such as humic substances, were 30∼60% of DOC in Yodo rivers and about 25% in the northern basin of Lake Biwa. The contribution of hydrophobic acids, such as humic substances, to the THM formation potential was about 70% in Yodo rivers, while it was about 30% in the northern basin of Lake Biwa, which was almost same as the contribution of hydrophilic DOM to THM formation potential. Hydrophilic neutral DOM was 15∼20% of DOC in Lake Biwa, and its contribution of THM formation potential was about 40%, which was larger than those of hydrophobic acids and hydrophilic DOM. The THM formation potential per organic carbon unit of hydrophilic fractions in the northern basin of Lake Biwa were two-times that in rivers. These results suggest that the kinds of hydrophilic DOM in Lake Biwa may be different from those in rivers.<br>

収録刊行物

  • 分析化学

    分析化学 54 (9), 923-928, 2005

    公益社団法人 日本分析化学会

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