二酸化セレンを用いた石炭の加熱処理と処理炭の液化反応特性
書誌事項
- タイトル別名
-
- Low-Temperature Atmospheric Pyrolysis of Coal in Presence of SeO2 and Liquefaction of Pyrolyzed Coal.
この論文をさがす
説明
Gas evolution from coal heated at a fairly low temperature in the presence of SeO2 and liquefaction behavior of the treated coal were examined for different coals. During atmospheric pyrolysis of coal with SeO2, gas evolution was observed at extremely low temqeratures below 473 K. The gas was shown to consist of CO, CO2 and H2O. Combined with the gas evolution characteristics with gas composition from various aromatic model compounds, those gases were supposed to be originated mostly from carboxyl and methyl groups in coal and oxygen from SeO2. The solid residue after the pyrolysis was liquefied using a sufficient amount of tetralin as a solvent under 10MPa of nitrogen at 723K. The results clearly showed that the SeO2-treated coals give higher yields of pyridineand benzenesolubles than their parent coal due to improved coal reactivity and catalytic effects of SeO2 and/or Se formed during pyrolysis.
収録刊行物
-
- 日本エネルギー学会誌
-
日本エネルギー学会誌 72 (8), 778-786, 1993
一般社団法人 日本エネルギー学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282679334462336
-
- NII論文ID
- 130003825023
-
- ISSN
- 18826121
- 09168753
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可