Formation of La(CH<SUB>3</SUB>COO)<SUB>2</SUB>(OH) by Glycothermal Treatment of L a n thanum Acetate Sesquihydrate and Its Thermal Decomposition Behavior

  • INOUE Masashi
    Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
  • KOMINAMI Hiroshi
    Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
  • OTSU Hiroyuki
    Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
  • INUI Tomoyuki
    Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

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Other Title
  • 酢酸ランタン1.5水和物のグリコサーマル処理によるLa(CH<SUB>3</SUB>COO)<SUB>2</SUB>(OH)の生成およびその熱分解挙動
  • 酢酸ランタン1.5水和物のグリコサーマル処理によるLa(CH3COO)2(OH)の生成およびその熱分解挙動
  • サクサン ランタン 1.5 スイワブツ ノ グリコサーマル ショリ ニ ヨル
  • Special Articles on Technology and Its Characterization for Synthesis of Inorganic Materials. Formation of La(CH3COO)2(OH) by Glycothermal Treatment of Lanthanum Acetate Sesquihydrate and Its Thermal Decomposition Behavior.

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Abstract

Glycothermal treatment of lanthanum acetate sesquihydrate in 1, 4-butanediol at 300 °C was examined and found to afford lanthanum diacetate hydroxide (La(CH3COO)2(OH)), which was confirmed by 13C-NMR spectrum (Fig.5), IR spectrum(Fig.4), elemental analysis (Table 2), and thermal analysis.

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1991 (10), 1254-1260, 1991-10-10

    The Chemical Society of Japan

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