書誌事項
- タイトル別名
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- Estimation of Carbon Aromaticity for Asphaltenes by Elemental Analysis and Proton NMR
- アスファルテン ノ タンソ ホウコウゾクセイ ノ ゲンソ ブンセキ オヨビ プロトン NMR カラ ノ ヨソク
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説明
The structure of asphaltene is an important factor for investigating the reactivity of heavy hydrocarbons. For the evaluation of asphaltene, elemental analysis and NMR analysis are commonly applied. However, such analyses are sometimes limited due to too small sample size. Especially, 13C-NMR analysis for the determination of carbon aromaticity (fa) requires about 100mg of asphaltene while elemental analysis and 1H-NMR analysis requires only 10mg or less. In addition, 13C-NMR analysis takes quite a long time for the measurement. It is well known that H/C atomic ratio has a strong relationship with fa, but it has relatively weak relationship with molecular structure. Therefore, we studied a statistical estimation method for fa of hepane-insolubles (asphaltene) from the results of elemental analysis and 1H-NMR analysis using 45 worldwide vacuum resides (VR). As a result, fa was estimated within a error of 0.04 using H/C, N/C, S/C and O/C atomic ratios obtained by an elemental analysis and hydrogen distribution obtained by 1H-NMR. The difference between observed number of aromatic rings per unit structure and estimated ones is within one. Those results are quite effective because only 20-30 mg of samples are necessary to obtain fa, and the data set for the average molecular structure analysis can be obtained from very small sample size obtained by a preparative GPC, for example.
収録刊行物
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- 日本エネルギー学会誌
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日本エネルギー学会誌 88 (7), 586-591, 2009
一般社団法人 日本エネルギー学会
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詳細情報 詳細情報について
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- CRID
- 1390282679334672512
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- NII論文ID
- 130004540944
- 10025985455
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- NII書誌ID
- AN10373883
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- COI
- 1:CAS:528:DC%2BD1MXhtVCgsbjK
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- ISSN
- 18826121
- 09168753
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- NDL書誌ID
- 10373918
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- 本文言語コード
- ja
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- NDLサーチ
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