Determination of Fullerene in Aquatic Environment by High-performance Liquid Chromatography-Mass Spectrometry
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- KOSUGI Yuki
- Tokyo Metropolitan Institute of Public Health
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- FUJIE Satoko
- Tokyo Metropolitan Institute of Public Health
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- SUZUKI Toshinari
- Tokyo Metropolitan Institute of Public Health
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- HOSAKA Mitsugu
- Tokyo Metropolitan Institute of Public Health
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- OGATA Akio
- Tokyo Metropolitan Institute of Public Health
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- NAKAE Dai
- Tokyo Metropolitan Institute of Public Health
Bibliographic Information
- Other Title
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- 液体クロマトグラフー質量分析による水環境中フラーレンの定量
- エキタイ クロマトグラフ : シツリョウ ブンセキ ニ ヨル ミズ カンキョウ チュウ フラーレン ノ テイリョウ
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Abstract
The analysis for fullerene (C60) in aquatic environment by LC/MS after the liquid-liquid extraction using hexane was established. The instrumental detection limit of C60 was 0.5 μg/L under this LC/MS conditions. As for liquid-liquid extraction, C60 was extracted at high extraction efficacy with hydrophobic solvents such as n-hexane, toluene, and benzene. On the other hand, solid phase extraction gave low extraction efficacy with any products investigated. The recovery rates of C60 in water samples by LC/MS after liquid-liquid extraction using n-hexan were 92-107% and the coefficients of variation were 4-13%. Preliminary examination of tap water of our institute and water samples from Tama-river basin did not detect C60 at the method detection limit of 1 ng/L.
Journal
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- Journal of Environmental Chemistry
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Journal of Environmental Chemistry 24 (2), 51-55, 2014
Japan Society for Environmental Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390282679345866112
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- NII Article ID
- 130004840672
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- NII Book ID
- AN10547099
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- ISSN
- 18825818
- 09172408
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- NDL BIB ID
- 025618663
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed