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- 内田 博久
- 東京農工大学工学部化学システム工学科
書誌事項
- タイトル別名
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- Solubility Characteristics of Aromatic Compound Isomers in Supercritical Carbon Dioxide and Their Application to an Advanced Separation.
- チョウリンカイ 2サンカタンソ ニ タイスル ホウコウゾク カゴウブツ イセイタイ ノ ヨウカイ トクセイ ト コウド ブンリ エ ノ オウヨウ
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The solubility characteristics of aromatic compound isomers in supercritical carbon dioxide and the microscopic structures of supercritical carbon dioxide around the aromatic compound isomers were studied using the Monte Carlo simulation with a group contribution site model. Calculated solubilities were in good agreement with experimental data and the solubilities of isomers can also be quantitatively distinguished by the model. The microscopic structures of supercritical carbon dioxide around the aromatic compound isomers were found to be different because of the screen effect of substituents. The adsorption separation of aromatic compound isomers dissolved in supercritical carbon dioxide using zeolites, a process called “supercritical phase adsorption separation”, was newly proposed and the method was found to be effective for the separation of the isomers.
収録刊行物
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- 高圧力の科学と技術
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高圧力の科学と技術 11 (2), 137-144, 2001
日本高圧力学会
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詳細情報 詳細情報について
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- CRID
- 1390282679357639936
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- NII論文ID
- 10007140504
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- NII書誌ID
- AN10452913
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- ISSN
- 13481940
- 0917639X
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- NDL書誌ID
- 5800127
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可