Pressure-Induced Changes of SO4 Sites in LiNaSO4 Crystal.

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  • Pressure Induced Changes of SO4 Sites i

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Abstract

Hydrostatic pressure-dependent Raman scattering studies in the range 0. 0 - 9. 66 Gpa were carried out in LiNaSO4 at room temperature in order to investigate its phonon spectra in relation to the phase transition in the crystal. From the behavior of v1 (SO4) modes for A1 species, we observe that the LiNaSO4 undergoes two phase transitions: one at ∼ 2 GPa and the other for P>5. 5 GPa.

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