The Reaction of 3-Cyano-2-methyl-1-phenylisothiourea with Isocyanate, Isothiocyanate and Carbodiimide

DOI Web Site Web Site 7 References
  • SUYAMA Takayuki
    Department of Applied Chemistry, Faculty of Engineering, Kanagawa Institute of Technology;
  • KIMURA Akifumi
    Department of Applied Chemistry, Faculty of Engineering, Kanagawa Institute of Technology;
  • KIUCHI Yasuyuki
    Department of Applied Chemistry, Faculty of Engineering, Kanagawa Institute of Technology;

Bibliographic Information

Other Title
  • 3-Cyano-2-methyl-1-phenylisothiourea とイソシアナート,イソチオシアナートおよびカルボジイミドとの反応
  • 3 Cyano 2 methyl 1 phenylisothiourea ト

Search this article

Description

It was clarified that 3-cyano-2-methyl-1-phenylisothiourea (1) reacted with silver nitrate in the presence of triethylamine to give rise to N-cyano-N'-phenylcarbodiimide (2), which reacted with 1 to give 2-cyanoimino-4-[(N2-cyano-An-phenylamidino)imino]-6-methylthio-1, 3-dipheny1-1, 2, 3, 4tetrahydro-1, 3, 5-triazine (3). In a similar manner, compound 1 reacted with two molar amounts of phenyl isocyanate, phenyl isothiocyanate and diphenylcarbodiimide in the presence of triethylamine to afford corresponding tetrahydro-1, 3, 5-triazines 11, 12 and 13 respectively.

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1996 (9), 845-848, 1996-09-10

    The Chemical Society of Japan

References(7)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top