Reaction of Alkylphenols with Cyanuric Chloride-<i>N</i>, <i>N</i>-Dimethylformamide Adduct

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  • アルキルフェノールとシアヌル酸クロリド-N,N-ジメチルホルムアミド付加物との反応
  • アルキルフェノールとシアヌル酸クロリド‐　Ｎ，Ｎ‐ジメチルホルムアミド付加物との反応

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Description

The reaction of alkylphenols(2)with cyanuric chloride-DMF adduct has been investigated. When the reactions were carried out at 30-40°C, where cyanuric chloride reacts with DMF to give 1 : 2 adduct, the corresponding formates of (2)were obtained. On the other hand, at 60-70°C, N2-(alkylphenoxycarbony1)-N1, N1-dimethylformamidines(3)were obtained. The hydrolyses of(3)in dilute acidic ethanol gave N-formylcarbamates (5)or carbamates(6). Reductions of(3)with NaBH4 in methanol afforded dimethylaminomethylcarbamates(7).

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1980 (3), 303-308, 1980-03-10

    The Chemical Society of Japan

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