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Reaction of Alkylphenols with Cyanuric Chloride-<i>N</i>, <i>N</i>-Dimethylformamide Adduct
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- MORIMURA Syoji
- Central Research Laboratories, Sankyo Co., Ltd
Bibliographic Information
- Other Title
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- アルキルフェノールとシアヌル酸クロリド-N,N-ジメチルホルムアミド付加物との反応
- アルキルフェノールとシアヌル酸クロリド‐ N,N‐ジメチルホルムアミド付加物との反応
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Description
The reaction of alkylphenols(2)with cyanuric chloride-DMF adduct has been investigated. When the reactions were carried out at 30-40°C, where cyanuric chloride reacts with DMF to give 1 : 2 adduct, the corresponding formates of (2)were obtained. On the other hand, at 60-70°C, N2-(alkylphenoxycarbony1)-N1, N1-dimethylformamidines(3)were obtained. The hydrolyses of(3)in dilute acidic ethanol gave N-formylcarbamates (5)or carbamates(6). Reductions of(3)with NaBH4 in methanol afforded dimethylaminomethylcarbamates(7).
Journal
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- NIPPON KAGAKU KAISHI
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NIPPON KAGAKU KAISHI 1980 (3), 303-308, 1980-03-10
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679365991680
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- NII Article ID
- 130004156667
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- ISSN
- 21850925
- 03694577
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed