書誌事項
- タイトル別名
-
- Syntheses and Nonlinear Optical Properties of Tribenzamide Derivatives
- Special Articles on Organic and Inorganic Optical Materials. Syntheses and Nonlinear Optical Properties of Tribenzamide Derivatives.
抄録
To develop high SHG active materials with short cut-off wavelengths, “umbrella-shaped”tribenzamide derivatives were investigated. Crystals of these umbrella type materials are expected to show molecular columns due to van der Waals interactions. Tribenzamide ( 1)gave a powder SHG efficiency 1.5 times that of urea, and itsλis 330 nm in methanol. In the β calculation of 1 by the ab initio STO-3 G CPHF method, the β component of the direction along umbrella shaft was the largest. However in the crystal state, the component disappeared due to antiparallel alignment of packing columns. In other para-substituted tribenzamide derivatives with methyl and methoxy substituents, only two compounds showed SHG efficiency.
収録刊行物
-
- 日本化学会誌（化学と工業化学）
-
日本化学会誌（化学と工業化学） 1992 (10), 1261-1263, 1992-10-10
公益社団法人 日本化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282679367159424
-
- NII論文ID
- 130004159776
-
- ISSN
- 21850925
- 03694577
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可