Preparation of Graphite Intercalation Compounds of Fluorine and Copper(II) Fluoride

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Bibliographic Information

Other Title
  • フッ素とフッ化銅(II)の黒鉛層間化合物の合成
  • ふっ素とふっ化銅（ＩＩ）の黒鉛層間化合物の合成

Description

The 1 st stage graphite intercalation compounds of fluorine and copper(II) fluoride, CxF(CuF2), (x=5-13, y=0.01-0.07) were prepared at temperatures between 20 and 343°C; their identity periods were in the range of 9.3, -9.4Å, which was almost the same as those for the intercalation compounds containing A1F3 or MgF2. ESCA spectra showed that the chemical bond similar to that of graphite fluoride increased around the surface of the compounds with increasing reaction temperature. On the basis of F-NMR measurement, it was found that fluorine atoms in the bulk of the intercalation compound existed in pseudo-liquid state.

Journal

  • NIPPON KAGAKU KAISHI

    NIPPON KAGAKU KAISHI 1983 (2), 283-286, 1983-02-10

    The Chemical Society of Japan

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