書誌事項
- タイトル別名
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- Formation of expandable fluorine micas-aluminum phosphate complexes.
抄録
The formation of the complex between synthetic fluorine micas, Li-taeniolite [LiMg2Li (Si4O10)F2] and Na-F-hectorite [Na1/3Mg2 2/3Li1/3(Si4O10)F2], and aluminum phosph ate was studied at various reaction conditions in order to elucidate the factors affecting the reaction and mechanism of complex formation. The complexes were formed from the suspension of fluorine micas in the solution of AlCl3, Ca(OH)2 and H3PO4 in certain concentration ranges. The compositions of interlayered materials and basal spacings of the complexes varied with the concentration of solution, the reaction time, and the particle size and layer charge of starting samples. The interlayered materials can be generally expressed as n[Al(PO4)x(OH)y], where PO4/Al ratio increases with reaction time and finally tends to converge to a value in the range of 0.8∼M.9. These results suggest that the aluminum phosphate complex is formed through an intermediate, so-called Al-hydroxy complex.
収録刊行物
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- 日本化学会誌（化学と工業化学）
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日本化学会誌（化学と工業化学） 1985 (9), 1773-1775, 1985
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679367451520
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- NII論文ID
- 130004158263
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- ISSN
- 21850925
- 03694577
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可