Deoxygenative Reduction of Organometallic Compounds by Hydrosilanes -An Organometallic Approach to Catalytic CO Hydrogenation-
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- AKITA Munetaka
- Research Laboratory of Resources Utilization, Tokyo Institute of Technology
Bibliographic Information
- Other Title
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- ヒドロシランによる有機金属錯体の脱酸素還元反応 -触媒的CO水素化反応への有機金属化学からのアプローチ-
- ヒドロシラン ニ ヨル ユウキ キンゾク サクタイ ノ ダツサンソ カンゲン
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Description
Reduction of organometallic compounds by hydrosilanes (HnSiR4-n) is studied. Because the H-Si bond in hydrosilanes shows reactivity similar to the H-H bond and, in addition to this feature, the Si part may display Lewis acidic property to activate oxygen-containing functional groups, it is expected that hydrosilanes can reduce oxygen-containing intermediates. As a result of our study, successful reproduction of elementary steps of catalytic CO hydrogenation (e. g. the carbon-chain propagation step of the Pichler-Schulz mechanism, methanation via the Fischer-Tropsch mechanism) is realized on discrete transition metal complexes.
Journal
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- NIPPON KAGAKU KAISHI
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NIPPON KAGAKU KAISHI 1998 (12), 783-793, 1998-12-10
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679367607936
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- NII Article ID
- 10001981929
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- NII Book ID
- AN00186595
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- ISSN
- 21850925
- 03694577
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- NDL BIB ID
- 4622729
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed