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- ASAHARA Teruzo
- Institute of Industrial Science, University of Tokyo
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- SENO Manabu
- Institute of Industrial Science, University of Tokyo
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- SHIMOZATO Yasuyuki
- Institute of Industrial Science, University of Tokyo
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- SHIMA Eiji
- Institute of Industrial Science, University of Tokyo
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- OTSU Masayuki
- Institute of Industrial Science, University of Tokyo
Bibliographic Information
- Other Title
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- 共役ジエン類のエポキシ化反応
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Description
Theepoxidatianreactionofconjugateddieneswithperbenzoicacidinchloroformwasexzminedkinetically. Ethylsorbate, butadiene, isoprene, trans-1, 3-pentadiene, 2, 3-dimethylbutadiene, 4-methyl-1, 3-pentadieneand2, 4-dimethyl-1, 3-pentadienewereusedasconjugated dienes. Fortheepoxidat onofbutadienederivatives(C=C-C=C)giving1, 2-epoxy-3-butenes, allnearHammett-typerelationwasconfirmedwhenOkamoto-Brown'ssubstituentconstant σ ρ +wasapphedto1-, 2-and4-substituent, andσ m+wasappliedto3-substituentasshown inFig.4. Thevalueofρ was-3.83.
Journal
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- NIPPON KAGAKU KAISHI
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NIPPON KAGAKU KAISHI 1972 (7), 1251-1255, 1972-07-10
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679394205184
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- NII Article ID
- 130004154217
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- ISSN
- 21850925
- 03694577
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed