Gelator Capable of Generating Rotaxane-Cross-link (Topological Cross-link)

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  • TAKATA Toshikazu
    Department of Organic and Polymeric Materials, Tokyo Institute of Technology

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Other Title
  • ロタキサン架橋（空間結合架橋）を生み出すゲル化剤
  • ロタキサン カケハシ(クウカン ケツゴウ カケハシ)オ ウミダス ゲルカザイ

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Description

As for gels possessing rotaxane-cross-links (or topological cross-links) of which characteristics are movable polymer chains at the cross-link points, that have recently collected much attention, the synthetic methods of them are summarized mainly from the viewpoint of gelator. In addition, the application of the methods to the synthesis of gels showing thermo-responsibility and recyclability and their properties are described for the discussion on the meaning of the rotaxane-cross-link.

Journal

  • Oleoscience

    Oleoscience 13 (2), 57-65, 2013

    Japan Oil Chemists' Society

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