Determination of the Kinetics and Heats of the Consecutive Thermal Decomposition of Solid by Simultaneous DTA-TGA Method
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- Ito Naotsugu
- National chem. Laboratory for Ind.
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- Obata Kenzaburo
- National chem. Laboratory for Ind.
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- Hakuta Toshikatsu
- National chem. Laboratory for Ind.
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- Yoshitome Hiroshi
- National chem. Laboratory for Ind.
Bibliographic Information
- Other Title
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- DTA‐TGA同時解析による固体の逐次熱分解反応の反応速度および分解熱の決定
- DTA TGA ドウジ カイセキ ニヨル コタイ ノ チクジ ネツ ブンカイ
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Description
Equations were derived for determining the kinetic parameters (Z, E, n) and heat of reaction ΔH with respect to the consecutive thermal decomposition of solid by using the simultaneous DTA-TGA technique, and the theoretical DTA and TGA curves were predicted by integrating the equations numerically with varying input parameters.<BR>As a result, for evaluating the heat of decomposition from the DTA peak, it was evident that the error in measuring the DTA peak area becomes large with increase in the degree of heat capacity changes of the sample and the value of cp1/|ΔH1|, which lead to large changes on the imaginary base line. On the other hand, it was found that the kinetic parameters can be obtained by analyzing the TGA curve directly.
Journal
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- KAGAKU KOGAKU RONBUNSHU
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KAGAKU KOGAKU RONBUNSHU 9 (4), 434-440, 1983
The Society of Chemical Engineers, Japan
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Details 詳細情報について
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- CRID
- 1390282679484928000
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- NII Article ID
- 130000881468
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- NII Book ID
- AN00037234
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- COI
- 1:CAS:528:DyaL3sXltFWnu70%3D
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- ISSN
- 13499203
- 0386216X
- http://id.crossref.org/issn/0386216X
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- NDL BIB ID
- 2599668
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed