書誌事項
- タイトル別名
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- Displacement reaction of thiophenol on 1-bromooctane by phase transfer catalysis through liquid-liquid flat interface.
- エキエキ テイ カイメン オ トオシテ ノ ソウカン イドウ ショクバイ サヨ
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The mass-transfer effect on reaction of 1-bromooctane with thiophenoxide ion, catalyzed by tetrabutylammonium cation, was studied in an agitated vessel with a plane interface.<BR>In both phases-benzene and aqueous solution of 2N sodium hydroxide-the phase equilibrium of catalyst or volume ratio of the two phases and the reaction rate were measured by changing the concentration of catalyst, interfacial area or agitation speed.<BR>Results of the equilibrium and kinetics studies indicated that the diffusion rates of tetrabutylammonium thiophenoxide, its dimer tetrabutylammonium bromide were much lower than the chemical reaction rate in a heterogeneous system.
収録刊行物
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- 化学工学論文集
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化学工学論文集 13 (6), 788-794, 1987
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679485697920
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- NII論文ID
- 130000869743
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- NII書誌ID
- AN00037234
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- ISSN
- 13499203
- 0386216X
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- NDL書誌ID
- 3156154
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可