Measurement and Correlation of Isoprene-Maleic Anhydride Reaction Rate in Hexane-Nitrobenzene Mixture.

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  • INOUE YUSUKE
    Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University
  • NISHIKAWA TOMOTAKA
    Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University
  • SATO MASAKI
    Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University
  • IWAI YOSHIO
    Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University
  • ARAI YASUHIKO
    Department of Chemical Systems and Engineering, Graduate School of Engineering, Kyushu University
  • KATO HARUO
    Department of Chemical Engineering Ichinoseki National College of Technology

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Other Title
  • ヘキサン‐ニトロベンゼン混合溶媒中でのイソプレンと無水マレイン酸の反応速度の測定ならびに溶液モデルによる相関
  • ヘキサンーニトロベンゼン コンゴウ ヨウバイ チュウ デ ノ イソプレン ト ムスイ マレインサン ノ ハンノウ ソクド ノ ソクテイ ナラビニ ヨウエキ モデル ニ ヨル ソウカン

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Reaction rates for the Diels-Alder reaction of isoprene with maleic anhydride in the hexanenitrobenzene mixed solvent were measured at 308.15 K. By using a reaction rate equation derived from the transition state theory coupled with the regular solution model, the reaction rates obtained previously at 293.88 K and in the present study were correlated. The dependence of reaction rates on the composition of hexane-nitrobenzene mixed solvent was correlated with fairly good agreement by introducing interaction parameters estimated with vapor-liquid equilibria into the regular solution model.

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