Relative Cage-Occupancy of CO2-Methane Mixed Hydrate.
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- Nakano Shinya
- Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
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- Ohgaki Kazunari
- Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
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Abstract
The composition and cage-occupancy of guest species in a CO2-methane mixed hydrate system are investigated by use of Raman spectroscopy. A single crystal of mixed gas hydrate shows the homogeneous mole fraction in equilibrium. The CO2 molecule is entrapped into the M-cage prior to the S-cage comparing to methane. The relative cage-occupancy of CO2 and methane in the structure-I hydrate lattice is scarcely affected by pressure condition.
Journal
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 33 (3), 554-556, 2000
The Society of Chemical Engineers, Japan
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Details 詳細情報について
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- CRID
- 1390282679541850112
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- NII Article ID
- 130000020395
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- NII Book ID
- AA00709658
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- COI
- 1:CAS:528:DC%2BD3cXksVOgt7o%3D
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- ISSN
- 18811299
- 00219592
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- NDL BIB ID
- 5418466
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed