Solvent Extraction Equilibrium of Zinc(II) from Ammonium Chloride Medium by CYANEX 923 in Solvesso 100.
-
- ALGUACIL FRANCISCO JOSÉ
- Centro Nacional de Investigaciones Metalúrgicas (CSIC), Ciudad Universitaria
-
- MARTÍNEZ SUSANA
- Centro Nacional de Investigaciones Metalúrgicas (CSIC), Ciudad Universitaria
書誌事項
- タイトル別名
-
- Solvent Extraction Equilibrium of Zinc 2 from Ammonium Chloride Medium by CYANEX 923 in Solvesso 100
この論文をさがす
抄録
The extraction equilibrium of zinc in ammonium chloride medium with CYANEX 923 (phosphine oxides mixture) in Solvesso 100 has been investigated. The distribution coefficient of zinc was independent of the equilibrium pH; this independence being attributable to a solvation extraction mechanism. Slope analysis for the system using dilute zinc solution reveals that two moles of CYANEX 923 react with one mol of zinc. The stoichiometric factor of water in the extraction reaction is found to be 2, whereas experimental data indicated that two chloride ions are involved for each metal extracted. The extraction reaction is exothermic (ΔH° = −42.0 kJ mol-1).
収録刊行物
-
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
-
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 34 (11), 1439-1442, 2001
公益社団法人 化学工学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282679542202624
-
- NII論文ID
- 130000020268
-
- NII書誌ID
- AA00709658
-
- COI
- 1:CAS:528:DC%2BD3MXovFKqsbg%3D
-
- ISSN
- 18811299
- 00219592
-
- NDL書誌ID
- 5992984
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可