A Simple Method of Evaluating Alkanolamine Absorbents for Post-Combustion CO₂ Capture
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- Goto Kazuya
- Research Institute of Innovative Technology for the Earth
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- Yamada Hidetaka
- Research Institute of Innovative Technology for the Earth
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- Higashii Takayuki
- Research Institute of Innovative Technology for the Earth
書誌事項
- タイトル別名
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- A Simple Method of Evaluating Alkanolamine Absorbents for Post-Combustion CO<sub>2</sub> Capture
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抄録
Carbon dioxide (CO2) capture by aqueous amine solutions has been developed to facilitate CO2 capture and storage (CCS) technology. In the present study, gas scrubbing tests were performed using twelve alkanolamine absorbents, including a variety of primary, secondary, and tertiary amines, with some hindered amines. The resulting absorption characteristics are discussed in the context of the pKa values of the amines as well as the 13C-NMR spectra and reaction kinetics. The absorption rate (α′CO<sub>2</sub>) was revealed to correlate strongly with the reaction rate constant (k2) of the CO2-amine second order reaction. A linear equation, log10(k2)=A·α′CO<sub>2</sub>+B, was derived for the aqueous amine solutions evaluated in the current study. For the experimental conditions of 20% CO2 gas and 2 mol/L amine solution, the constants A and B were 0.0285 and −0.4564 for the primary and secondary amines, and 0.0107 and −0.3726 for the hindered amines, respectively. Furthermore, the correlation between the reaction rate constants and pKa values of the hindered amines could be expressed as ln(k2)=0.436pKa+12.92−5,379/T.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 47 (6), 463-470, 2014
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679544557056
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- NII論文ID
- 130004145820
- 40020131979
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- NII書誌ID
- AA00709658
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 025602210
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可