Studies on Hydration Reaction Rates of Various Size CaO Particles for Chemical Heat Storage/Pump
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- Zhang Hongxia
- Department of Urban Environment Systems, Graduate School of Engineering, Chiba University
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- Ogura Hironao
- Department of Urban Environment Systems, Graduate School of Engineering, Chiba University
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From the viewpoints of energy and environmental problems in the world, the development of effective energy utilization technologies such as chemical heat storage/pump and their practical uses are required. In this paper, the hydration reaction rates of various size CaO particles for calcium oxide/water chemical heat storage/pump were studied using thermogravimetric analysis based on the grain model. Firstly, we calculate a reaction rate equation using the coefficient ηr for the particle size effects as model I, which is based on our previous method for calcium sulfate considering the effects of the particle size. Furthermore, the catalyst effectiveness factor taking into account the mass transfer resistance within the porous particles, the particle expansion and the pore size changes along with the hydration reaction is proposed and introduced into a new reaction model II, because the shapes of the calculated data in model I and the experimental data are different. As a result, it is demonstrated that the intraparticle mass transfer resistance increases as the particle size increases. Further, the proposed applied grain model I enables evaluation of this experiment roughly. Furthermore, the applied grain catalyst model II shows that the calculated conversion lines are consistent with the experimental data for 106–1,000 µmϕ particles considering the pressure drop inside the particles by the introduction of the catalyst effectiveness factor. In addition, the expansion ratio of the CaO particles is lower than that of the grains in the reaction model II.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 47 (7), 587-594, 2014
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679544880384
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- NII論文ID
- 130004056959
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- NII書誌ID
- AA00709658
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 025602368
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可