Oxidative Coupling of Methane in the LSM/YSZ/LaAlO SOFC Reactor
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- Kiatkittipong Worapon
- Department of Chemical Engineering, Nagoya University Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Chulalongkorn University
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- Tagawa Tomohiko
- Department of Chemical Engineering, Nagoya University
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- Goto Shigeo
- Department of Chemical Engineering, Nagoya University
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- Assabumrungrat Suttichai
- Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Chulalongkorn University
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- Praserthdam Piyasan
- Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Chulalongkorn University
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Oxidative coupling of methane was studied in a solid oxide fuel cell (SOFC) tube type reactor. La0.85Sr0.15MnO3/8 mol% Y2O3-ZrO2/La1.8Al0.2O3 (abbreviated as LSM/YSZ/LaAlO) were used as a cathode, electrolyte and anode. The C2 selectivity and the methane conversion were 91.7% and 23.7% at 1273 K, respectively. The kinetic rate expression was proposed with two different oxygen species. The internal resistance of cell could be lumped and estimated by maximum power transfer theorem. The effect of external load was investigated both in experiments and calculations. The proposed modeling agreed well with the experimental results.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 37 (12), 1461-1470, 2004
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679546700288
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- NII論文ID
- 130000019615
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- NII書誌ID
- AA00709658
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 7196183
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可