Intra-ion-pair Electron Transfer Mechanism for Photolysis of Diphenyliodonium Salt Sensitized by 9,10-Dmethoxyanthracene-2-sulfonate Counteranion

DOI PDF 14 Citations 7 References

Abstract

Diphenyliodonium 9,10-dimethoxyanthracene-2-sulfonate is photochemically dissociated to give 9,10-dimethoxyanthracene-2-sulfonic acid. The dissociation is considered to proceed via an intra-ion-pair electron transfer from 9,10-dimethoxyanthracene moiety to iodonium moiety. The counteranion acts as both spectral sensitizer for diphenyliodonium ion and precursor for photo-acid generator.

Journal

  • Chemistry Letters

    Chemistry Letters 20 (11), 1869-1872, 1991

    The Chemical Society of Japan

Citations (14)*help

See more

References(7)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top