Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Nitrile Oxides to an Achiral Allyl Alcohol Utilizing Diisopropyl Tartrate as a Chiral Auxiliary
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- Shimizu Makoto
- Department of Chemistry, Faculty of Science, Kanazawa University
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- Ukaji Yutaka
- Department of Chemistry, Faculty of Science, Kanazawa University
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- Inomata Katsuhiko
- Department of Chemistry, Faculty of Science, Kanazawa University
書誌事項
- 公開日
- 1996
- DOI
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- 10.1246/cl.1996.455
- 10.1002/chin.199643032
- 公開者
- 公益社団法人 日本化学会
この論文をさがす
説明
The catalytic asymmetric 1,3-dipolar cycloaddition of nitrile oxides to an achiral allyl alcohol was achieved by the use of a catalytic amount of diisopropyl (R,R)-tartrate as a chiral auxiliary to afford the corresponding (R)-2-isoxazolines with high enantioselectivity. In order to realize reproducible higher stereoselection, the addition of a small amount of ethereal compound such as 1,4-dioxane was crucial.
収録刊行物
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- Chemistry Letters
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Chemistry Letters 25 (6), 455-456, 1996
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679550180096
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- NII論文ID
- 10002603919
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- NII書誌ID
- AA00603318
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- COI
- 1:CAS:528:DyaK28XjsVKhtLY%3D
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- ISSN
- 13480715
- 03667022
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可
