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Reaction of Tungsten Metal Powder with Hydrogen Peroxide to Form Peroxo Tungstates, An Useful Precursor of Proton Conductor
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- Nakajima Hitoshi
- Institute of Industrial Science, The University of Tokyo
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- Kudo Tetsuichi
- Institute of Industrial Science, The University of Tokyo
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- Mizuno Noritaka
- Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo
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Description
The title reaction was investigated by 183W NMR, Raman and TOF-MASS spectroscopy. Peroxotungstates with peroxo/W = 2 and peroxo/W = 1 were formed. The latter compounds are previously unknown. The removal of hydrogen peroxide from the reaction solution by the decomposition with Pt net promoted the polymerization of these species.
Journal
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- Chemistry Letters
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Chemistry Letters 26 (8), 693-694, 1997
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679552051328
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- NII Article ID
- 10002613373
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- NII Book ID
- AA00603318
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- COI
- 1:CAS:528:DyaK2sXlt1aktb8%3D
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed
