SYNTHESES OF (±)-CONFERTIFOLIN AND (±)-ISODRIMENIN

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  • ChemInform Abstract: SYNTHESES OF (.+‐.)‐CONFERTIFOLIN AND (.+‐.)‐ISODRIMENIN

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Description

A large scale synthesis of (±)-confertifolin and (±)-isodrimenin was achieved starting from β-ionone via the tricyclic furan derivative. Oxidation of this common intermediate with Pb(OAc)4 followed by pyrolysis afforded the former as a main product. The latter was prepared as a main product by NaBH4 reduction of (±)-winterin derived from the same intermediate.

Journal

  • Chemistry Letters

    Chemistry Letters 8 (11), 1365-1368, 1979-11-05

    The Chemical Society of Japan

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