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Spin Trapping Studies of Peroxyl Radicals. Detection of the Reactive Intermediates for Oxidation Generated from O<SUB>2</SUB><SUP>−•</SUP> and Sulfonyl, Sulfinyl, and Phosphoryl Chlorides
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- Kim Yong Hae
- Department of Chemistry, Korea Advanced Institute of Science and Technology
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- Lim Sang Chul
- Department of Chemistry, Korea Advanced Institute of Science and Technology
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- Hoshino Mikio
- The Institute of Physical and Chemical Research
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- Ohtsuka Yasuo
- The Institute of Physical and Chemical Research
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- Ohishi Takeshi
- The Institute of Physical and Chemical Research
Bibliographic Information
- Other Title
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- Spin Trapping Studies of Peroxyl Radicals. Detection of the Reactive Intermediates for Oxidation Generated from O2−• and Sulfonyl, Sulfinyl, and Phosphoryl Chlorides
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Description
The spin trapping studies by ESR have demonstrated that O2−• efficiently reacts with 2-nitrobenzenesulfonyl chloride, 2-nitrobenzenesulfinyl chloride, and diphenylphosphoryl chloride, to result in the formation of their peroxyl radicals, some of which have been key intermediates for site-selective oxidation of certain organic molecules and argued whether they exist as anion and/or radical form.
Journal
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- Chemistry Letters
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Chemistry Letters 18 (1), 167-170, 1989
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679559695744
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- NII Article ID
- 130004153430
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- COI
- 1:CAS:528:DyaL1MXktlyksro%3D
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed
