Spin Trapping Studies of Peroxyl Radicals. Detection of the Reactive Intermediates for Oxidation Generated from O2−• and Sulfonyl, Sulfinyl, and Phosphoryl Chlorides

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タイトル別名
  • Spin Trapping Studies of Peroxyl Radicals. Detection of the Reactive Intermediates for Oxidation Generated from O<SUB>2</SUB><SUP>−•</SUP> and Sulfonyl, Sulfinyl, and Phosphoryl Chlorides

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説明

The spin trapping studies by ESR have demonstrated that O2−• efficiently reacts with 2-nitrobenzenesulfonyl chloride, 2-nitrobenzenesulfinyl chloride, and diphenylphosphoryl chloride, to result in the formation of their peroxyl radicals, some of which have been key intermediates for site-selective oxidation of certain organic molecules and argued whether they exist as anion and/or radical form.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 18 (1), 167-170, 1989

    公益社団法人 日本化学会

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