New Class of Catalysts for Alternating Copolymerization of Alkylene Oxide and Carbon Dioxide

  • Okada Atsushi
    Department of Chemistry, Keio University
  • Kikuchi Satoshi
    Department of Chemistry, Keio University
  • Nakano Koji
    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
  • Nishioka Kiyoshi
    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
  • Nozaki Kyoko
    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
  • Yamada Tohru
    Department of Chemistry, Keio University

書誌事項

公開日
2010
DOI
  • 10.1246/cl.2010.1066
公開者
公益社団法人 日本化学会

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説明

Di(ketoiminato)cobalt complexes have been employed for the alternating copolymerization of alkylene oxide and carbon dioxide. These complexes exhibited not only good catalytic activity for polycarbonate synthesis, but also an excellent selectivity for the formation of carbonate linkages without any ether linkage in the reaction of several alkylene oxides, especially for ethylene oxide.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 39 (10), 1066-1068, 2010

    公益社団法人 日本化学会

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