DECARBOXYLATION REACTION VI. REACTION OF α-ALKYLIDENEMALONONITRILES WITH TRICHLOROACETIC ACID. A NEW 1,1-DICHLOROCYCLOPROPANE FORMATION THROUGH β-TRICHLOROMETHYLATION

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It has been found that highly electron-deficient carbon-carbon double bond conjugated, in the main, with two cyano groups undergoes 1,1-dichlorocyclopropane formation by reacting with trichloroacetic acid. This reaction is presumed not to involve dichlorocarbene, but trichloromethylated intermediate.

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  • Chemistry Letters

    Chemistry Letters 6 (5), 553-556, 1977-05-05

    The Chemical Society of Japan

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