Stereocontrolled Total Synthesis of (−)-Gleenol Using Claisen Rearrangement of Sterically Congested Dihydropyran
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- Nakazaki Atsuo
- Faculty of Pharmaceutical Sciences, Tokyo University of Science
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- Era Tomohiro
- Faculty of Pharmaceutical Sciences, Tokyo University of Science
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- Kobayashi Susumu
- Faculty of Pharmaceutical Sciences, Tokyo University of Science
書誌事項
- タイトル別名
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- Stereocontrolled Total Synthesis of (-)-Gleenol Using Claisen Rearrangement of Sterically Congested Dihydropyran
- ChemInform Abstract: Stereocontrolled Total Synthesis of (‐)‐Gleenol Using Claisen Rearrangement of Sterically Congested Dihydropyran.
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説明
A stereocontrolled total synthesis of enantiomerically pure (−)-gleenol using an improved substrate to construct the spiro[4.5]decane through Claisen rearrangement has been achieved. The most striking feature of this synthesis is that the rearrangement of sterically congested dihydropyran, bearing all requisite substituents with proper stereochemistry, afforded the fully functionalized spiro[4.5]decane in a single step.
収録刊行物
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- Chemistry Letters
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Chemistry Letters 37 (7), 770-771, 2008
公益社団法人 日本化学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282679562223232
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- NII論文ID
- 130004425201
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- ISSN
- 13480715
- 15222667
- 03667022
- 09317597
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可
