Photochemical Cleavage of the Axial Group Attached to the Central Carbon Atom of Triazatriangulene

DOI PDF 被引用文献2件 参考文献20件
  • Yokoyama Soichi
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Hirose Takashi
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Matsuda Kenji
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

書誌事項

公開日
2015
資源種別
journal article
DOI
  • 10.1246/cl.140897
公開者
公益社団法人 日本化学会

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説明

Photocleavage reaction of triazatriangulene (TATA) leuco derivatives bearing axial substituents proceeded quantitatively in polar solvents with quantum yields (Φr) of up to 0.56. The photoreaction can easily be detected by the red color and yellow fluorescence originating from the photogenerated TATA cation. Electron-withdrawing groups on the axial substituent effectively suppress the photoreaction, in a particular case, Φr became less than 0.01.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 44 (1), 76-78, 2015

    公益社団法人 日本化学会

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