Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C–H Bond Cleavage
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- Hirano Koji
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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- Bolm Carsten
- Institute of Organic Chemistry, RWTH Aachen University
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- Miura Masahiro
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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- Yokoyama Yuki
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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- Unoh Yuto
- Department of Applied Chemistry, Faculty of Engineering, Osaka University JST, ACT-C
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- Bohmann Rebekka Anna
- Department of Applied Chemistry, Faculty of Engineering, Osaka University Institute of Organic Chemistry, RWTH Aachen University
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- Satoh Tetsuya
- Department of Applied Chemistry, Faculty of Engineering, Osaka University JST, ACT-C Department of Chemistry, Graduate School of Science, Osaka City University
書誌事項
- 公開日
- 2015
- 資源種別
- journal article
- DOI
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- 10.1246/cl.150444
- 10.1002/chin.201607108
- 公開者
- 公益社団法人 日本化学会
この論文をさがす
説明
Rhodium-catalyzed direct coupling of benzothioamides with alkenes proceeds smoothly involving ortho-C–H bond cleavage. The thioamides also couple with alkynes under similar conditions accompanied by desulfurization and C–N bond cleavage to produce indenone derivatives.
収録刊行物
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- Chemistry Letters
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Chemistry Letters 44 (8), 1104-1106, 2015
公益社団法人 日本化学会
