Catalytic Asymmetric Cyanation of Alkylideneindolenines Generated from Sulfonylalkylindoles

DOI DOI PDF 研究データあり 被引用文献3件 参考文献22件
  • Ohmatsu Kohsuke
    Institute of Transformative Bio-Molecules (WPI-ITbM), and Department of Applied Chemistry, Graduate School of Engineering, Nagoya University
  • Furukawa Yukino
    Institute of Transformative Bio-Molecules (WPI-ITbM), and Department of Applied Chemistry, Graduate School of Engineering, Nagoya University
  • Nakaguro Daigo
    Institute of Transformative Bio-Molecules (WPI-ITbM), and Department of Applied Chemistry, Graduate School of Engineering, Nagoya University
  • Ooi Takashi
    Institute of Transformative Bio-Molecules (WPI-ITbM), and Department of Applied Chemistry, Graduate School of Engineering, Nagoya University CREST, Japan Science and Technology Agency (JST)

書誌事項

公開日
2015
DOI
  • 10.1246/cl.150581
  • 10.1002/chin.201616129
公開者
公益社団法人 日本化学会

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説明

The catalytic asymmetric phase-transfer cyanation of alkylideneindolenines, generated in situ from sulfonylalkylindoles, was developed. In the presence of sodium cyanide and a catalytic amount of chiral 1,2,3-triazolium salt, a series of sulfonylalkylindoles can be transformed into the corresponding chiral 3-sec-alkylindoles with good-to-high levels of efficiency and enantioselectivity.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 44 (10), 1350-1352, 2015

    公益社団法人 日本化学会

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