Development of Far-UV Spectroscopy for Liquid and Solid and Its Application to Analytical Chemistry

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  • MORISAWA Yusuke
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University
  • TACHIBANA Shin
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University
  • YASUNAGA Manaka
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University
  • MITSUOKA Motoki
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University
  • SATO Harumi
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University
  • IKEHATA Akifumi
    National Food Research Institute, National Agriculture and Food Research Organization (NARO)
  • HIGASHI Noboru
    KURABO Industries Ltd.
  • OZAKI Yukihiro
    Department of Chemistry, School of Science and Technology, Kwansei Gakuin University

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Other Title
  • 液体・固体用遠紫外分光法の開発とその分析化学への応用
  • エキタイ ・ コタイヨウエンシガイ ブンコウホウ ノ カイハツ ト ソノ ブンセキ カガク エ ノ オウヨウ

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Description

Spectroscopic studies in the far-UV (FUV) region (120–200 nm) are very attractive for both basic sciences and applications, since various kinds of electronic transitions are observed in the region. However, because of very large absorption coefficients, full-scale FUV spectra for liquids and solids could not be measured easily. We have recently developed a totally new FUV spectrometer based on attenuated total reflection (ATR) that enables us to measure the full-scale spectra of liquid and solid samples in the 140–200 nm region. In this paper, at first we outline the characteristics and advantages of the FUV spectroscopy, and then discuss our studies on the development of an ATR-FUV spectrometer and its applications to analytical chemistry. At the end, we introduce our newly developing time-resolved ATR-FUV spectrometer.

Journal

  • BUNSEKI KAGAKU

    BUNSEKI KAGAKU 61 (7), 591-603, 2012

    The Japan Society for Analytical Chemistry

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