Study of the Vapor-Liquid Coexistence Curve and the Critical Curve for Nonazeotropic Refrigerant Mixture R152a + R114 System

  • KABATA Yasuo
    Graduate School of Science and Technology, Keio University (3-14-1, Hiyoshi, Kohoku-ku, Yokohama 223)
  • HIGASHI Yukihiro
    Department of Mechanical Engineering, Iwaki Meisei University (5-5-1, Iino, Chuodai, Iwaki 970)
  • UEMATSU Masahiko
    Department of Mechanical Engineering, Keio University (3-14-1, Hiyoshi, Kohoku-ku, Yokohama 223)
  • WATANABE Koichi
    Department of Mechanical Engineering, Keio University (3-14-1, Hiyoshi, Kohoku-ku, Yokohama 223)

Bibliographic Information

Other Title
  • 非共沸混合冷媒R152a+R114系の気液共存曲線および臨界軌跡に関する研究

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Description

Measurements of the vapor-liquid coexistence curve in the critical region for the refrigerant mixture of R152a (CH3CHF2: 1, l-difluoroethane) +R 114 (CCIF2CCIF2 :1, 2-dichloro-1, 1, 2, 2-tetrafluoroethane) system were made by visual observation of the disappearance of the meniscus at the vapor-liquid interface within an optical cell. Forty-eight saturated densities along the vapor-liquid coexistence curve between 204 and 861 kg·m-3 for five different compositions of 10, 20, 50, 80 and 90 wt% R 152a were obtained in the temperature range 370 to 409 K. The experimental errors of temperature, density, and mass fraction were estimated within ±10mK, ±0.5% and +0.05 %, respectively. On the basis of these measurements, the critical parameters of five different compositions for the R 152a +R 114 system were determined in consideration of the meniscus disappearance level as well as intensity of the critical opalescence. In accordance with the previous results of three other refrigerant mixtures, i.e., R 12 +R 22 system, R 22 +R 114 system and R 13B1 + R 114 system, the coexistence curve and critical curve on the temperature-density diagram for binary refrigerant mixtures were discussed. In addition, correlations of its composition dependence for this system were proposed.

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Details 詳細情報について

  • CRID
    1390282679641644544
  • NII Article ID
    130004566316
  • DOI
    10.11322/tjsrae.5.97
  • ISSN
    2185789X
    13444905
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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