UV-VIS spectra and photoinitiation behaviors of acylphosphine oxide and bisacylphosphine oxide derivatives in unfilled, light-cured dental resins

DOI NDLデジタルコレクション Web Site PubMed 被引用文献7件 参考文献31件 オープンアクセス
  • IKEMURA Kunio
    Department of Research and Development, Shofu Inc.
  • ICHIZAWA Kensuke
    Department of Research and Development, Shofu Inc.
  • YOSHIDA Mariko
    Department of Research and Development, Shofu Inc.
  • ITO So
    Department of Research and Development, Shofu Inc.
  • ENDO Takeshi
    Molecular Engineering Institute, Kinki University Chemical Resources Laboratory, Tokyo Institue of Technology

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The aims of this study were to investigate the photoinitiation behaviors of acylphosphine oxide (APO) and bisacylphosphine oxide (BAPO) derivatives in comparison to D,L-camphorquinone (CQ)/tertiary amine (EDAB) system. Fifty six kinds of experimental unfilled, light-cured resins were prepared using APO, BAPO, CQ, EDAB, resin monomers, and adhesive monomers. The measurements of ultraviolet-visible (UV-VIS) spectroscopy, photopolymerization with differential scanning calorimeter (photo-DSC) and degree of conversion (DC) determination were performed. Results showed that the UV-VIS spectra of all APO and BAPO derivatives possessed λmax ranging between 365 and 416 nm. Their photoinitiation behaviors were not influenced by acidic adhesive monomers formulated in unfilled Bis-GMA-based resins (p<0.05). Although BAPO exhibited higher reactivity than CQ/EDAB in unfilled 6-methacryloyloxyhexcyl phosphonoacetate (6-MHPA)/ 2-hydroxyethyl methacrylate (HEMA) and 6-MHPA/glycerol monomethacrylate (GM)-based resins, it was found that there were no statistically significant differences in DC (%) between BAPO [44.2(6.5)–51.2(4.3)] and CQ/EDAB [42.4(4.4)–47.5(3.7)] (p<0.05). It was concluded that APO and BAPO photoinitiators exhibited reactivity comparable to that of CQ/tertiary amine system.

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