書誌事項
- タイトル別名
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- Structure and properties of borate crosslinked poly(vinyl alcohol) gel films.
- ホウサン カキョウ ニ ヨル ポリビニルアルコールゲル フィルム ノ コウゾウ
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Poly (vinyl alcohol) (PVA) reacts with borate ions to give a thermoreversible gel. In this work, gel films (PVA-G) were successfully prepared by drying this gel or by soaking PVA films (PVA-O; crosslink-free PVA films) in a solution containing borate ions. On the other hand, the crosslinks formed in PVA-G can be removed by soaking PVA-G in an acid solution. The mechanical properties and structure of PVA-G were investigated by means of dynamic viscoelastic, wide angle X-ray diffraction, hot water resistance and thermogravimetric measurements, and were compared with those of PVA-O.<br>The results of dynamic viscoelastic measurements show that PVA-G retains a high value in storage modulus up to ca. 200°C which are different from PVA-O. In addition, there appeared a mechanical dispersion around ca. 220°C. Wide angle X-ray diffraction patterns show that the crystallite size of PVA-G is smaller than PVA-O. The characteristic behaviors in viscoelasticity are explained by the presence of crosslinks and/or crystallite size. Hot water resistance of PVA-G was also found to be improved by the introduction of crosslinks.
収録刊行物
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- 繊維学会誌
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繊維学会誌 48 (2), 74-83, 1992
社団法人 繊維学会
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詳細情報 詳細情報について
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- CRID
- 1390282679805260160
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- NII論文ID
- 130004205093
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- NII書誌ID
- AN00131651
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- ISSN
- 18842259
- 00379875
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- NDL書誌ID
- 3759307
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
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- 抄録ライセンスフラグ
- 使用不可