絹フィブロインおよび羊毛繊維に対するメタクリル酸メチルのグラフト共重合反応の動力学的考察

DOI Web Site Web Site 被引用文献1件

書誌事項

タイトル別名
  • KINETICS OF GRAFT COPOLYMERIZATION OF METHYL METHACRYLATE IN SILK FIBROIN AND WOOL KERATIN FIBERS
  • キヌ フィブロイン オヨビ ヨウモウ センイ ニ タイスル メタクリルサン メチル ノ グラフト キョウジュウゴウ ハンノウ ノ ドウリキガクテキ コウサツ

この論文をさがす

抄録

The kinetics of graft copolymerization of methyl methacrylate onto silk fibroin or wool keratin fibers in aqueous LiBr-K2S2O8 redox system was studied.<br>It was found that the grafting occurred by the radicalotoropy to the active centers of silk fibroin or wool keratin fibers from the radicals formed by the redox system, not by the chain transfer mechanism. From the experimental results at different temperatures, the activation energies for reaction steps were calculated. From these results, the thiol groups on wool keratin are considered to be predominantly in the center of grafting, but it is suggested that the grafting site of silk fibroin fibers differs from that of wool keratin fibers.

収録刊行物

  • 繊維学会誌

    繊維学会誌 23 (12), 595-601, 1967

    社団法人 繊維学会

被引用文献 (1)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ