Simple and Rapid Determination of Zinc, Cadmium, Copper and Lead in Soil Samples by Stripping Voltammetry Using Mercury Film Microelectrode
-
- ISHIYAMA Takashi
- Center for Environmental Science in Saitama
-
- TAKAHASHI Motoyuki
- Center for Environmental Science in Saitama
-
- SUZUKI Koji
- GL Sciences Inc.
-
- FURUSHO Yoshiaki
- GL Sciences Inc.
Bibliographic Information
- Other Title
-
- 水銀膜微小電極を用いたストリッピングボルタンメトリーによる土壌中亜鉛,カドミウム,銅及び鉛の簡易迅速定量
- スイギン マク ビショウ デンキョク オ モチイタ ストリッピング ボルタンメトリー ニ ヨル ドジョウ チュウ アエン カドミウム ドウ オヨビ ナマリ ノ カンイ ジンソク テイリョウ
Search this article
Abstract
A simple and rapid method was developed for the determination of zinc, cadmium, copper and lead at the mg·kg-1 level in soil samples by anodic stripping voltammetry using a mercury film microelectrode (surface area, 240μm2). Pre-electrolysis was performed at -1.3V vs. Ag/AgCl for 2min with stirring in a 0.1mol·l-1 acetic acid-sodium acetate buffer solution (pH 4.2). After the stirring was stopped, anodic stripping voltammograms for deposits were recorded in the potential range of -1.3 to 0.15V vs. Ag/AgCl at a scan rate of 50mV·s-1 in a differential pulse mode. Calibration curves (peak height vs. concentration) were linear (correlation coefficient >0.999) over the 0.2 to 10μg·l-1 concentration range with a relative standard deviation of approximately 5% for 1μg·l-1 (n=5). The detection limits (3σ) calculated from the repeated determination of 0.1μg·l-1 metal ions for a deposition time of 2min ranged from 0.04 to 0.07μg·l-1. Possible interferences were evaluated. This method was successfully applied to the simultaneous determination of zinc, cadmium, copper and lead in several soil samples without any separation steps of matrix elements. The time required for an analysis was within 3min.
Journal
-
- Journal of Japan Society on Water Environment
-
Journal of Japan Society on Water Environment 27 (11), 715-720, 2004
Japan Society on Water Environment
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390282680056740736
-
- NII Article ID
- 10013786789
-
- NII Book ID
- AN10372439
-
- COI
- 1:CAS:528:DC%2BD2MXitFOntA%3D%3D
-
- ISSN
- 18813690
- 09168958
-
- NDL BIB ID
- 7149138
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed