Continious Determination of Organic Water Pollutans by Chemiluminescent Method.

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  • KITANO Masaru
    Department of Apllied Materials Science, College of Engineering, University of Osaka Prefecture
  • FUJIMORI Keiichi
    Department of Apllied Materials Science, College of Engineering, University of Osaka Prefecture
  • TAKENAKA Norimichi
    Department of Apllied Materials Science, College of Engineering, University of Osaka Prefecture
  • BANDOW Hiroshi
    Department of Apllied Materials Science, College of Engineering, University of Osaka Prefecture
  • MAEDA Yasuaki
    Department of Apllied Materials Science, College of Engineering, University of Osaka Prefecture

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  • 化学発光法を用いた環境水中の有機汚濁化合物による汚染度の測定
  • カガク ハッコウホウ オ モチイタ カンキョウスイチュウ ノ ユウキ オダク

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Abstract

A continious flow method for measurement of organic substances (OS) in water has been developed on the chemiluminescent (CL) reaction between organic subustances and hydorgen peroxide in the presence of formaldehyde in alkaline solution. This CL method was characterized the CL intensity of polynucleated compounds were greater compared with saturated straightchain compounds (saturayed alcohol, acetic acid). The limit of detection for humic acid (HA) was 50 ppb (w/w) and the relative standard deviation for six measurements of 1.0 ppm (w/w) of HA was 1.6%. Cations such as Na+, K+, Mg2+ and Fe3+ and anions such as PO43-, NO3-, CO32-, SO42-, Cl- and Y- (NaEDTA) did not interfere with the detemination of HA. Addition of Mn (II) enhanced the CL intensity. Three results measured by CL, CODCr, TOC methods for natural water samples were in good agreement. The correlation coefficient of CL intensity to TOC and CODCr were 0.85 and 0.81, respectively.

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