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Structure and Properties of Polyfunctional Naphthalene-based Epoxy Resins
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- KAJI Masashi
- R & D Laboratories, Nippon Steel Chemical Co., Ltd.
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- ARAMAKI Takanori
- R & D Laboratories, Nippon Steel Chemical Co., Ltd.
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- NAKAHARA Kazuhiko
- R & D Laboratories, Nippon Steel Chemical Co., Ltd.
Bibliographic Information
- Other Title
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- 多官能型ナフタレン系エポキシ樹脂の構造と物性
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Description
Naphthalene-based epoxy resins were synthesized through epoxydation of polyhydroxy compounds obtained by the condensation reaction of naphthols or dihydroxynaphthalenes with condensing agents, i.e. formaldehyde, P-xylylene glycol and 2, 6-dimethylol-p-cresol, and the relation between the structure and properties of their cured products with phenol novolac was studied.<BR>The following results were obtained. The introduction of naphthalene nuclear into the resin structure was an effective way to decrease water absorption without losing heat resistance. The cured products from naphthalene-based epoxy resins gave smaller values in the linear thermal expansion coefficient than those from phenyl-ring epoxy resins. However, the linear expansion coefficient from the naphthalene-base cured resins reached almost the same value as that of phenol novolac-base resins, as a result of increasing crosslinking density in a glassy state near Tg above 200°C
Journal
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- Japan Thermosetting Plastic Industry Association
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Japan Thermosetting Plastic Industry Association 14 (4), 189-195, 1993
Japan Thermosetting Plastics Industry Association
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Details 詳細情報について
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- CRID
- 1390282680067225344
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- NII Article ID
- 130006886352
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- ISSN
- 21865361
- 03884384
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed