強磁性窒化物α″‐Ｆｅ１６Ｎ２構造の電子回折・電子顕微鏡法による研究とバンド計算による磁性評価
書誌事項
- タイトル別名
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- Electron Diffraction and Microscopy Study and Band Structure Calculation of Ferromagnetic Iron-Nitride .ALPHA."-Fe16N2.
- 強磁性窒化物α''-Fe16N2構造の電子回折・電子顕微鏡法による研究とバンド計算による磁性評価
- キョウジセイ チッカブツ アルファ Fe16N2 コウゾウ ノ デンシ カイセツ デンシ ケンビキョウホウ ニ ヨル ケンキュウ ト バンド ケイサン ニ ヨル ジセイ ヒョウカ
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The crystal structure of the α" phase in tempered Fe-N martensite was refined by means of single-crystal electron diffraction intensity analysis. Electron diffraction intensities recorded on imaging plates were compared with the intensities calculated to take account of dynamical. The crystal structure of α" belongs to the space group I4/mmm, and the lattice parameters are a = 0.572 and c = 0.631 nm. The positional parameters x for Fe(8h) and z for Fe(4e) are x = 0.220 and z = 0.303. On the basis of these structural data, electronic band structure calculations using full-potential LAPW method were performed for the Fe16N2. The average magnetic moment per Fe atom is about 2.2 μB, which is nearly equal to that of α-Fe. In high-resolution electron microscope images, α" regions in which the N concentration was less than that of Fe16N2 were observed locally between the Fe16N2 precipitates and the tempered matrix. The magnetic structure of the local non-stoichiometric α" phase is discussed in relation to the band structure.
収録刊行物
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- 日本応用磁気学会誌
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日本応用磁気学会誌 23 (3), 858-862, 1999
公益社団法人 日本磁気学会
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詳細情報 詳細情報について
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- CRID
- 1390282680069710592
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- NII論文ID
- 110002811591
- 130004478441
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- NII書誌ID
- AN0031390X
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- COI
- 1:CAS:528:DyaK1MXjtVCmsbc%3D
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- ISSN
- 18804004
- 02850192
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- NDL書誌ID
- 4672310
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- NDL-Digital
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
