One-pot Synthesis of End-functionalized Conjugated Polymers by Combined Acyclic Diene Metathesis (ADMET) Polymerization Using Molybdenum Catalyst with Wittig-type Coupling
-
- MIYASHITA Tomonari
- Dept. of Chemistry, Tokyo Metropolitan University
-
- INAGAKI Akiko
- Dept. of Chemistry, Tokyo Metropolitan University
-
- NOMURA Kotohiro
- Dept. of Chemistry, Tokyo Metropolitan University
Bibliographic Information
- Other Title
-
- モリブデン錯体触媒を用いる非環式ジエンメタセシス重合とWittig型カップリング反応による末端官能基化π共役ポリマーのone-pot精密合成
Search this article
Abstract
<p>Precise, one-pot synthesis of end-functionalized conjugated polymers, poly(9,9-di-n-octyl-fluorene vinylene)s (PFVs), have been prepared by acyclic diene metathesis (ADMET) polymerization followed by Wittig-type coupling with aldehyde in the presence of molybdenum-alkylidene catalyst, Mo(CHMe2Ph)(N-2,6-Me2C6H3)[OC(CH3)(CF3)2]2 (Mo cat.). Further addition of Mo cat. after the ADMET polymerization was necessary for completion of olefin metathesis (with the vinyl chain end) and for exclusive end-functionalization by the subsequent coupling. Various end-functionalities could be introduced without purification or isolation by this one-pot methodology.</p>
Journal
-
- Journal of the Japan Petroleum Institute
-
Journal of the Japan Petroleum Institute 59 (5), 197-203, 2016-09-01
The Japan Petroleum Institute
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390282680165638912
-
- NII Article ID
- 130005277205
-
- NII Book ID
- AA11590615
-
- ISSN
- 1349273X
- 13468804
-
- NDL BIB ID
- 027629670
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed