Crystal Structure of (1-Adamantylmethyl)trimethyl-ammonium Iodide

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  • UEDA Masato
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • NAKAGAWA Mitsuko
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • FUJIMORI Keiichi
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • MORIUCHI Takayo
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • SHIBUTANI Yasuhiko
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology

Description

The title compound, (1-adamantylmetyl)trimethyl-ammonium iodide (AdMeNMe3I), was synthesized, and its structure was investigated by X-ray crystallography. It was crystallized in the monoclinic space group P21/n with the following cell parameters: a = 7.573(2)Å, b = 13.935(3)Å, c = 14.1095(18)Å, β = 99.792(15)°, and Z = 4. The final residual factor was 0.0984. The compound exhibited a warped cavity of the adamantyl group due to an interaction with a quaternary ammonium group.

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