Crystal Structure of 1,3-Bis(4-nitrophenyl)triazenido- .KAPPA.2N1N3]-bis(triphenylphosphine)copper(I), [Cu(O2NC6H4NNNC6H4NO2)(C18H15P)2]

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The reaction between [CuCl(PPh3)3] and 1,3-bis(4-nitrophenyl)triazene deprotonated with metallic sodium in methanol yields crystalline [Cu(O2NC6H4NNNC6H4NO2)(C18H15P)2], the first mononuclear triazenide complex of Cu(I) including a [Cu(PPh3)2]+ fragment. The crystals belong to the monoclinic system, space group P21/c with the cell dimensions a = 15.8852(3), b = 11.9539(3), c = 23.2094(6)Å, β = 94.646(1)°, V = 4392.75(18)Å3, Z = 4. The crystal structure reveals a bidimensional assembling of complex molecules linked through intermolecular non-classical C-H…O hydrogen bonds.

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