Absorption, Translocation and Metabolism of Fluoroimide in Inu-apple Trees, <i>Malus prunifolia</i> BORKHOUSEN
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- OGAWA Kunihiko
- Mitsubishi-Kasei Institute of Toxicological and Environmental Sciences
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- AIZAWA Hiroyasu
- Mitsubishi-Kasei Institute of Toxicological and Environmental Sciences
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- YAMAUCHI Fumio
- Mitsubishi-Kasei Institute of Toxicological and Environmental Sciences
Bibliographic Information
- Other Title
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- イヌリンゴにおけるフルオルイミドの吸収, 移行および代謝
- イヌリンゴにおけるフルオルイミドの吸収,移行および代謝〔英文〕
- イヌリンゴ ニ オケル フルオルイミド ノ キュウシュウ イコウ オヨビ タイ
- Fate of Fluoroimide, <i>N</i>-(4-Fluorophenyl)-2, 3-dichloromaleimide (Part 1)
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Abstract
Fate of Fluoroimide, N-(4-fluorophenyl)-2, 3-dichloromaleimide, on/in Inu-apple trees (Males prunifolia BORKHOUSEN) was investigated using two 14C-labeled compounds at either benzene ring or carbonyl group. Half lives of Fluoroimide applied on the leaves and fruits were about 20 days and 30 days, respectively. It remained mainly unchanged on the applied surface and was slowly absorbed by the plant. Only 2% of applied Fluoroimide was translocated into the leaves 9 days after treatment, and 9% and 18% of applied radioactivity were absorbed and translocated into the leaves and fruits, respectively, after 93 days. A main metabolite of Fluoroimide was sodium 4-fluorodichloromaleanilate, a hydrolyzed compound of imide ring, that was identified by MS, IR, NMR and FX. Other four metabolites, such as 4-fluoroaniline, (E)-2, 3-dichloro-N-(4-fluorophenyl) acrylamide, N-(4-fluorophenyl) maleimide and N-(4-fluorophenyl) succinimide, were identified by cochromatography on tlc and MS, but residual amounts of these metabolites were quite low both in the leaves and fruits. It is considered that succinimide moiety of a reduced metabolite was derived from dichloromaleic acid portion of Fluoroimide, but not from the plant component.
Journal
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- Journal of Pesticide Science
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Journal of Pesticide Science 5 (1), 29-36, 1980
Pesticide Science Society of Japan
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Details 詳細情報について
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- CRID
- 1390282680186096896
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- NII Article ID
- 110001711455
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- NII Book ID
- AN00196227
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- ISSN
- 03851559
- 13490923
- 1348589X
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- NDL BIB ID
- 2567608
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- Data Source
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- JaLC
- IRDB
- NDL
- Crossref
- NDL-Digital
- CiNii Articles
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- Abstract License Flag
- Disallowed