水溶液中でのオクタクロロプロピルエーテルの光分解に関する速度論的解析

  • Shi Yan-hong
    Provincial Key Laboratory for Agri-Food Safety, Anhui Province, China, 
School of Resource & Environment, Anhui Agricultural University
  • Liao Min
    Provincial Key Laboratory for Agri-Food Safety, Anhui Province, China, 
School of Plant Protection, Anhui Agricultural University Department of Agronomy, Suzhou Vocational Technical College
  • Kiyota Hiromasa
    Graduate School of Environmental and Life Science, Okayama University
  • Cao Hai-qun
    Provincial Key Laboratory for Agri-Food Safety, Anhui Province, China, 
School of Plant Protection, Anhui Agricultural University Graduate School of Environmental and Life Science, Okayama University
  • Hua Ri-mao
    Provincial Key Laboratory for Agri-Food Safety, Anhui Province, China, 
School of Resource & Environment, Anhui Agricultural University
  • Tang Feng
    International Center for Bamboo & Rattan
  • Yue Yong-de
    International Center for Bamboo & Rattan

書誌事項

タイトル別名
  • Kinetics of octachlorodipropyl ether photolysis in aqueous solution

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説明

The photodegradation kinetics of octachlorodipropyl ether (OCDPE) in aqueous solution have been studied under select conditions. The photodegradation rate constants of OCDPE increase with the increases of temperature and pH. The photolysis rates of OCDPE in the investigated water follow the sequence of pure water>impoundment water>pond water>lake water. The photodegradation product of OCDPE is shown to be 2,3,3-trichloroprop-2-en-1-ol. We propose that the OCDPE photolytic pathways consist of dehydrochlorination and ether cleavage via ionic or radical mediated reaction.

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