A simple synthesis of the regiospecifically deuterium-labeled herbicide MCPA-isopropyl

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  • 位置選択的に重水素標識された除草剤MCPA-イソプロピルの簡便な合成

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Abstract

In order to investigate the metabolism of the herbicide MCPA-isopropyl [isopropyl 2-(4-chloro-2-methylphenoxy)acetate] in the environment, two isotopologues of this regiospecifically deuterium-labeled in selected positions compound were synthesized. The synthesized compounds were labeled at the methylene group, isopropyl 2-(4-chloro-2-methylphenoxy)[2,2-2H2]acetate, and at the isopropyl group, [2H7]isopropyl 2-(4-chloro-2-methylphenoxy)acetate.

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